Authors: Rodriguez-Aguado, E; Infantes-Molina, A; Talon, A; Storaro, L; Leon-Reina, L; Rodriguez-Castellon, E; Moretti, E

Article.
Int. J. Hydrog. Energy. vol: 44. page: 0360-3199.
Date: JAN 8. 2019.
Doi: 10.1016/j.ijhydene.2018.11.050.

Abstract:
Gold nanoparticles precipitated-deposited on titania nanostructures (1.0 wt% nominal loading) were studied in the preferential CO oxidation in excess of H-2 at room temperature and atmospheric pressure, both in dark and under simulated solar light irradiation. Titania supports were synthesized by means of two hydrothermal methods markedly acid and basic, giving rise to rutile nanorods and anatase deformed nanorods structures, respectively. Characterization techniques such as N-2 physisorption, XRD, XPS, DRUV-vis, HRTEM and XRF were performed in order to study the chemical, structural and optical properties of the catalysts. Well defined rutile nanorods structures were obtained from the acidic treatment allowing a regular distribution of gold nanoparticles and resulting quite active in the CO-PROX reaction. In particular the sample from the acidic synthetic approach calcined at 700 degrees C displayed the best results as it was highly selective to CO2 under both dark and simulated solar light irradiation. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved..