Highlights

The combination of covalent and ionic exchange immobilizations enables the coimmobilization on vinyl sulfone activated supports and the reuse of the most stable immobilized enzyme

Authors: Arana-Pena, S; Carballares, D; Morellon-Sterling, R; Rocha-Martin, J; Fernandez-Lafuente, R

Article.
Int. J. Biol. Macromol.. vol: 199. page: 0141-8130.
Date: feb-28. 2022.
Doi: 10.1016/j.ijbiomac.2021.12.148.

Abstract:
The coimmobilization of lipases from Rhizomucor miehei (RML) and Candida antarctica (CALB) has been intended using agarose beads activated with divinyl sulfone. CALB could be immobilized on this support, while RML was not. However, RML was [read more]

The bone-degrading enzyme machinery: From multi-component understanding to the treatment of residues from the meat industry

Authors: Fernandez-Lopez, L; Sanchez-Carrillo, S; Garcia-Moyano, A; Borchert, E; Almendral, D; Alonso, S; Cea-Rama, I; Miguez, N; Larsen, O; Werner, J; Makarova, KS; Plou, FJ; Dahlgren, TG; Sanz-Aparicio, J; Hentschel, U; Bjerga, GEK; Ferrer, M

Article.
Comp. Struct. Biotechnol. J… vol: 19. page: 2001-0370.
Date: . 2021.
Doi: 10.1016/j.csbj.2021.11.027.

Abstract:
Many microorganisms feed on the tissue and recalcitrant bone materials from dead [read more]

Recent progress on bimetallic NiCo and CoFe based electrocatalysts for alkaline oxygen evolution reaction: A review

Authors: Gebreslase, GA; Martinez-Huerta, MV; Lazaro, MJ

Review.
J. Energy Chem.. vol: 67. page: 2095-4956.
Date: APR. 2022.
Doi: 10.1016/j.jechem.2021.10.009.

Abstract:
The deployment of hydrogen as an energy carrier is found to be a vital alternative fuel for the future. It is expected that water electrolysis, powered by renewable energy sources, be able to scale-up hydrogen production. However, the reaction kinetic of [read more]

Cubic versus hexagonal – phase, size and morphology effects on the photoluminescence quantum yield of NaGdF4:Er3+/Yb3+ upconverting nanoparticles

Authors: Quintanilla M, Hemmer E, Marques-Hueso J, Rohani S, Lucchini G, Wang M, R. Zamani R, Roddatis V, Speghini A, S. Richards B and Vetrone F

Article.
Nanoscale, 2022,14, 1492-1504
Date: . 2022.
Doi: 10.1039/D1NR06319G.

Abstract:
Upconverting nanoparticles (UCNPs) are well-known for their capacity to convert near-infrared light into UV/visible light, benefitting various applications where light triggering is required. At the nanoscale, [read more]

Thermo-photo production of hydrogen using ternary Pt-CeO2-TiO2 catalysts: A spectroscopic and mechanistic study

Authors: Caudillo-Flores, U; Barba-Nieto, I; Munoz-Batista, MJ; Meira, DM; Fernandez-Garcia, M; Kubacka, A

Article.
Chem. Eng. J.. vol: 425. page: 1385-8947.
Date: DEC 1. 2021.
Doi: 10.1016/j.cej.2021.130641.

Abstract:
The gas phase thermo-photo production of hydrogen from methanol:water mixtures was tested using platinum ceria-titania ternary solids. This contribution focusses on the analysis of the role of ceria and the usefulness of combining heat [read more]

Graphene oxide activates B cells with upregulation of granzyme B expression: evidence at the single-cell level for its immune-modulatory properties and anticancer activity

Authors: Orecchioni, M; Fusco, L; Mall, R; Bordoni, V; Fuoco, C; Rinchai, D; Guo, S; Sainz, R; Zoccheddu, M; Gurcan, C; Yilmazer, A; Zavan, B; Menard-Moyon, C; Bianco, A; Hendrickx, W; Bedognetti, D; Delogu, LG

Article; Early Access.
Nanoscale. vol: . page: 2040-3364.
Date: . .
Doi: 10.1039/d1nr04355b.

Abstract:
We recently found by single-cell mass cytometry that ex vivo human B cells [read more]

Structure and evolutionary trace-assisted screening of a residue swapping the substrate ambiguity and chiral specificity in an esterase

Authors: Cea-Rama, I; Coscolin, C; Katsonis, P; Bargiela, R; Golyshin, PN; Lichtarge, O; Ferrer, M; Sanz-Aparicio, J

Article.
Comp. Struct. Biotechnol. J… vol: 19. page: 2001-0370.
Date: . 2021.
Doi: 10.1016/j.csbj.2021.04.041.

Abstract:
Our understanding of enzymes with high substrate ambiguity remains limited because their large active sites allow substrate docking freedom to an extent that seems incompatible with stereospecificity. One possibility is [read more]

Defective UiO-66(Zr) as an efficient catalyst for the synthesis of bio jet-fuel precursors via aldol condensation of furfural and MIBK

Authors: de la Flor, D; Lopez-Aguado, C; Paniagua, M; Morales, G; Mariscal, R; Melero, JA

Article.
J. Catal.. vol: 401. page: 0021-9517.
Date: SEP. 2021.
Doi: 10.1016/j.jcat.2021.07.006.

Abstract:
The production of jet-fuel precursors from furfural (FUR) via aldol-condensation with methyl-isobutyl ketone (MIBK) over a defective UiO-66(Zr) catalyst is presented. The resultant C11 adduct (FuMe) would allow the selective production of branched alkanes [read more]

Recent developments in the use of peroxygenases – Exploring their high potential in selective oxyfunctionalisations

Authors: Hobisch, M; Holtmann, D; de Santos, PG; Alcalde, M; Hollmann, F; Kara, S

Review.
Biotechnol. Adv.. vol: 51. page: 0734-9750.
Date: nov-01. 2021.
Doi: 10.1016/j.biotechadv.2020.107615.

Abstract:
Peroxygenases are an emerging new class of enzymes allowing selective oxyfunctionalisation reactions in a cofactor-independent way different from well-known P450 monooxygenases. Herein, we focused on recent de-velopments from organic synthesis, molecular biotechnology and reaction engineering [read more]

Effect of N-doping and carbon nanostructures on NiCu particles for hydrogen production from formic acid

Authors: Carrales-Alvarado, DH; Lopez-Olmos, C; Dongil, AB; Kubacka, A; Guerrero-Ruiz, A; Rodriguez-Ramos, I

Article.
Appl. Catal. B-Environ.. vol: 298. page: 0926-3373.
Date: DEC 5. 2021.
Doi: 10.1016/j.apcatb.2021.120604.

Abstract:
A series of NiCu based catalysts were prepared using different carbon nanostructure as support and loading 2.5 wt% of each metal. The studied nanocarbon materials were: reduced graphene oxide (rGO), N-doped reduced graphene oxide [read more]

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