Publications 2022

Method for analyzing HR-TEM micrographs to propose and/or describe structures and their interaction in crystalline materials

Authors: Obeso-Estrella, R; Pawelec, B; Mota, N; Flores-Sanchez, LA; Quintana-Melgoza, JM; Yocupicio-Gaxiola, RI; Zepeda, TA

Article.
MethodsX. vol: 9. page: .
Date: . 2022.
Doi: 10.1016/j.mex.2022.101855.

Abstract:
A general and versatile method for the analysis and processing of HR-TEM data useful for several applications is presented. The first utility is to identify the structures seen in the micrographs; also can be extended [read more]

2022-11-10T09:51:47+01:00Categories: Publications 2022|Tags: |

Aqueous phase hydrogenation of maleic acid to succinic acid mediated by formic acid: the robustness of the Pd/C catalytic system

Authors: Orozco-Saumell, A; Mariscal, R; Iglesias, J; Maireles-Torres, P; Granados, ML

Article; Early Access.
Sustain. Energ. Fuels. vol: . page: 2398-4902.
Date: . .
Doi: 10.1039/d2se01073a.

Abstract:
Long-term liquid phase studies of the activity in the formic acid-mediated hydrogenation of MAc to SAc were conducted in a fixed bed continuous reactor for two relevant situations: neutralising maleic and formic acids with NaOH [read more]

Immobilization-stabilization of the dimeric D-amino acid oxidase from porcine kidney

Authors: Carballares, D; Fernandez-Lafuente, R; Rocha-Martin, J

Article.
Process Biochem.. vol: 122. page: 1359-5113.
Date: NOV. 2022.
Doi: 10.1016/j.procbio.2022.10.002.

Abstract:
This paper shows the immobilization of the dimeric D-amino acid oxidase (DAAO) following different methodologies. Immobilization on glyoxyl-agarose yielded activity recoveries under 5%, and it was discarded. The anion exchange on aminated supports permits the rapid enzyme immobilization, but its activity decreased [read more]

Highly Active and Stable Ni/La-Doped Ceria Material for Catalytic CO2 Reduction by Reverse Water-Gas Shift Reaction

Authors: Consuelo Alvarez-GalvanPablo G. LustembergFreddy E. OropezaBelén Bachiller-BaezaMartin Dapena OspinaMaría HerranzJesús CebolladaLaura Collado, José M. Campos-MartinVíctor A. de la Peña-O’SheaJosé A. Alonso, and M. Verónica Ganduglia-Pirovano.

Article.
ACS Appl. Mater. Interfaces
Date: oct-03. 2022.
Doi: https://doi.org/10.1021/acsami.2c11248

Abstract:
he design of an active, effective, and economically viable catalyst for CO2 conversion [read more]

2022-11-03T14:37:56+01:00Categories: Highlights, Publications 2022|

Switch off/switch on of a cysteinyl protease as a way to preserve the active catalytic group by modification with a reversible covalent thiol modifier: Immobilization of ficin on vinyl-sulfone activated supports

Authors: Morellon-Sterling, R; Bolivar, JM; Fernandez-Lafuente, R

Article.
Int. J. Biol. Macromol.. vol: 220. page: 0141-8130.
Date: nov-01. 2022.
Doi: 10.1016/j.ijbiomac.2022.08.155.

Abstract:
The immobilization of ficin (a cysteinyl proteases) on vinyl sulfone agarose produced its almost full inactivation. It was observed that the incubation of the free and immobilized enzyme in beta-mercaptoethanol produced a 20 % of enzyme activity recovery, suggesting that [read more]

Surface modification of Cu2O-CuO photocatalyst on Cu wire through decorating with TiO2 nanoparticles for enhanced visible light photocatalytic activity

Authors: Ansari, F; Sheibani, S; Fernandez-Garcia, M

Article.
J. Alloy. Compd.. vol: 919. page: 0925-8388.
Date: oct-25. 2022.
Doi: 10.1016/j.jallcom.2022.165864.

Abstract:
In this paper, the fabrication of Cu2O-CuO/TiO2 nanocomposite photocatalysts on Cu wire was performed successfully via chemical-thermal oxidation and sol-gel process. The chemical-thermal oxidations were applied for Cu2O-CuO nanostructure fabrication on the Cu wire surface. The sol-gel process was utilized for [read more]

Optimization of the immobilization of xylanase from Thermomyces lanuginosus to produce xylooligosaccharides in a batch type reactor

Authors: Alagoz, D; Varan, NE; Yildirim, D; Fernandez-Lafuente, R

Article.
Mol. Catal.. vol: 531. page: 2468-8231.
Date: OCT. 2022.
Doi: 10.1016/j.mcat.2022.112647.

Abstract:
The xylanase from Thermomyces lanuginosus was immobilized following very different protocols, using 3-aminopropyl (Xyl/CNT-NH2) and carboxylic acid (Xyl/CNT-C) functionalized multi-walled carbon nanotubes or after glutaraldehyde activation of CNT-NH2 (Xyl/CNT-Glu). It was also immobilized on carboxylic acid functionalized multi-walled carbon nanotubes [read more]

2022-11-09T17:49:34+01:00Categories: Publications 2022|Tags: , |

Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery

Authors: Naim, MT; Lara-Serrano, M; Romero, AF; Morales-delaRosa, S; Campos-Martin, JM; Moreno, JRA; Ocon, P

Article.
Arab. J. Chem.. vol: 15. page: 1878-5352.
Date: OCT. 2022.
Doi: 10.1016/j.arabjc.2022.104127.

Abstract:
Expanders, as lignosulfonates, are crucial for a good performance of Pb/acid batteries. In the process of discharge, the Pb and the PbO2 go to PbSO4. The formed PbSO4 is adsorbed on the surface [read more]

2022-11-09T17:46:33+01:00Categories: Publications 2022|Tags: , |

Recent advances in continuous reduction of furfural to added value chemicals

Authors: Richel, A; Maireles-Torres, P; Len, C

Article.
Curr. Opin. Green Sustain. Chem.. vol: 37. page: 2452-2236.
Date: OCT. 2022.
Doi: 10.1016/j.cogsc.2022.100655.

Abstract:
This report describes the recent advances in reduction of furfural to added-value chemicals under liquid phase and gas phase continuous flow systems using conventional activation and using electrochemical activation. The main biobased-chemicals obtained furfuryl alcohol, tetrahydrofurfuryl alcohol, 2-methylfuran and [read more]

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