Descripción
El Grupo de Diseño Molecular de Catalizadores Heterogéneos realiza investigación científica para resolver problemas tecnológicos actuales de alto impacto social. Desde este punto de vista, los problemas medioambientales, principalmente la eliminación catalítica de gases nocivos para la atmósfera y el tratamiento de aguas residuales, se abordan a través del diseño y desarrollo de catalizadores sólidos eficientes. Los conceptos de la química C1 se aplican a la obtención de compuestos químicos básicos, por ejemplo, hidrocarburos o gas de síntesis. La producción y el almacenamiento de hidrógeno se abordan con procesos libres de CO y la aplicación de reactores de membrana. La síntesis de compuestos químicos específicos (Química Fina) se realiza con catalizadores altamente selectivos, como en las reacciones de hidrogenación. Nuestros proyectos de producción a gran escala de nanotubos y grafenos de carbono puro pueden ser catalogados de aplicación tecnológica inmediata. En estos estudios se suele aplicar una gran variedad de técnicas y metodologías experimentales, entre las que destacan: técnicas espectroscópicas (Mössbauer, FTIR, XPS, XANES), análisis térmico (microcalorimetría, TG, TPR, TPD), técnicas analíticas (cromatografía de gases, espectrometría de masas), microscopía electrónica y difracción de rayos X. Finalmente, el estudio de los procesos superficiales y los mecanismos de reacción se lleva a cabo utilizando moléculas etiquetadas isotópicamente, por ejemplo, en un reactor de Análisis Temporal de Productos (TAP-2).
WEB site of the group: https://gdmch.csic.es/
Laboratorio de Química en Superficies
El laboratorio de Química en Superficies del grupo de Diseño Molecular de Catalizadores Heterogéneos (ICP-CSIC) dispone de un reactor de Temporal Analysis of Products (TAP-2) y de un microcalorímetro Tian-Calvet C80 con las características que se relacionan a continuación.
- Reactor TAP: es una técnica de resolución temporal para la caracterización cinética precisa de reacciones gas-sólido en catálisis, adsorción y otras aplicaciones. A diferencia de los dispositivos cinéticos convencionales, el transporte de gas en el reactor TAP se produce a través de la difusión de Knudsen, un régimen de transporte especial en el que las moléculas chocan con las paredes del reactor y las superficies catalíticas, pero no entre sí. Así, las reacciones en fase gaseosa que pueden interferir con las interacciones gas-sólido de interés se eliminan por completo. En un experimento TAP, se inyectan pulsos de intensidad ultrabaja en el microrreactor en condiciones de vacío. Se pueden utilizar diferentes moléculas sonda para distinguir ciertas reacciones de ruptura/formación de enlaces y se pueden utilizar experimentos largos de pulsos para seguir gradualmente los cambios en la composición del material (oxidación/reducción/desactivación) y el impacto resultante en la cinética.
- Microcalorímetro C80: El calorímetro está acoplado a un sistema volumétrico de vacío que permite el tratamiento de los catalizadores y la determinación de isotermas de adsorción y calores asociados. Se pueden utilizar diferentes gases para la identificación de la heterogeneidad energética superficial de los catalizadores metálicos o de la basicidad (acidez) superficial en óxidos metálicos.
El laboratorio ofrece dar apoyo a la investigación científica tanto interna (del ICP) como externa (de otros centros del CSIC, OPIs, universidades y empresas) mediante estas técnicas. Para la solicitud de servicio se deberá contactar con la persona responsable del laboratorio y se valorará la viabilidad de la medida. Las tarifas de los experimentos dada la diversidad y complejidad de estos serán acordadas para cada caso en particular.
Personal
Inmaculada Rodríguez Ramos – Jefe de Grupo
María Virtudes Morales Vargas – Personal
Conesa Alonso, José María – Personal
Jorge Moral Pombo – Personal
Projectos
«Catalysts for biocompounds hydrogenation with formic acid and for valorization of carbon dioxide», Financial Organization: Spanish AEI; Reference: PID2020-119160RB-C21; 2021-2024
«Biomass and CO2 valorisation to high value added chemicals», Financial Organization: H2020-MSCA-RISE-2020; Reference: 101008058 — BIOALL; 2021-2025
«Producción de hidrogeno a partir de ácido fórmico empleando calefacción magnética», Financial Organization: Spanish AEI; Reference: TED2021-130525A-I00; 2022-2024
Publicaciones
Synergistic, Dual Energy Source Production of Hydrogen using Ru-promoted Nitrogendoped Carbon Nanotubes
Uriel Caudillo-Flores, Damarys H. Carrales-Alvarado, Inmaculada Rodríguez-Ramos, Marcos Fernández-García and Anna Kubacka
Carbon, 221 (2024) 118903.
Cyclic performance in CO2 capture-methanation of bifunctional Ru with different base metals: Effect of the reactivity of COx ad-species
Enrique García-Bordejé, Ana Belén Dongil, Jorge Moral, José M. Conesa, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Journal of CO2 Utilization, 68 (2022) 102370.
Electrocatalytic Oxygen Reduction Reaction on 48-Tungsto-8-Phosphate Wheel Anchored on Carbon Nanomaterials
Hugo C. Novais, Bruno Jarrais, Ali Haider, Ulrich Kortz, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos, Cristina Freire, Diana M. Fernandes
Electrocatalysis, 14(2023) 294-305.
Selective hydrogenation reactions of 5-hydroxymethylfurfural over Cu and Ni catalysts in water: effect of Cu and Ni combination and the reagent purity
María V. Morales, José M. Conesa, Antonio J. Galvin, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Catalysis Today (2023).
Graphite supported heteropolyacid as a regenerable catalyst in the dehydration of 1-butanol to butenes
José M. Conesa, María V. Morales, Nadia Garcia-Bosch, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Catalysis Today, 420 (2023) 114017.
Graphene-Type Materials for the Dispersive Solid-Phase Extraction Step in the QuEChERS Method for the Extraction of Brominated Flame Retardants from Capsicum Cultivars
Virgínia Cruz Fernandes; Valentina F. Domingues; Marta S. Nunes; Renata Matos; Iwona Kuźniarska-Biernacka; Diana M. Fernandes; Antonio Guerrero-Ruiz; Inmaculada Rodríguez Ramos; Cristina Freire; Cristina Delerue-Matos
Journal of Agricultural and Food Chemistry, 71 (2023) 3898.
Dynamics of Pd Subsurface Hydride Formation and Their Impact on the Selectivity Control for Selective Butadiene Hydrogenation Reaction
Esther Asedegbega-Nieto, Ana Iglesias-Juez, Marco Di Michiel, Marcos Fernandez-Garcia, Inmaculada Rodriguez-Ramos and Antonio Guerrero-Ruiz
Nanomaterials, 13 (2023) 1099.
Reactivity of n-butene using carbon supported Mo carbide and Ni, Mo, Co phosphides catalysts
J.M. Fernández-Morales, L. Martínez-Quintana, A.B. Dongil, E. Asedegbega, E. Castillejos, I. Rodríguez-Ramos, A. Guerrero-Ruiz
Catalysis Today, 423 (2023) 114254.
Dual functional materials based on Ni and different alkaline metals on alumina for the cyclic stepwise CO2 capture and methanation
Enrique García-Bordejé, Ana Belén Dongil, José M. Conesa, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Chem. Eng. J,. 472 (2023) 144953.
Avoiding dry reforming control in direct CH4 and CO2 conversion operating at low-temperature below ambient pressure over AgPd4-Fe3-δO4 Nanocomposite
Elena Montejano-Nares, Blanca Martínez-Navarro, Eva Castillejos López, Esther Asedegbega-Nieto, Ángel Maroto Valiente, José M. Conesa Alonso, Inmaculada Rodríguez Ramos, Antonio R. Guerrero Ruíz, Francisco Ivars-Barceló
Chem. Eng. J. 474 (2023) 145373.
Efficient Nickel and Copper-based catalysts supported on modified graphite materials for the hydrogen production from formic acid decomposition.
Betina Faroldi, José María Conesa-Alonso, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos.
Applied Catalysis A, General, 629 (2022) 118419.
Effect of the carbon support and conditions on the carbothermal synthesis of Cu-molybdenum carbide and its application on CO2 hydrogenation to methanol
Ana Belén Dongil, Elodie Blanco, Juan José Villora-Picó, A. Sepúlveda-Escribano, I. Rodríguez-Ramos
Nanomaterials, 12 (2022) 1048.
Promotion of Ru or Ni on alumina catalysts with a basic metal for CO2 hydrogenation: effect of the type of metal (Na, K, Ba)
Enrique García-Bordejé, Ana Belén Dongil, José María Conesa-Alonso, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Nanomaterials, 12 (2022) 1052.
D.H. Carrales-Alvarado, C. López-Olmos, A.B. Dongil, A. Kubacka, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Applied Catalysis B: Environmental 298 (2021) 120604.
Study of the Interaction of an Iron Phthalocyanine Complex over Surface Modified Carbon Nanotubes
María Pérez-Cadenas, Esther Asedegbega-Nieto, Jonathan Carter, James A. Anderson, Inmaculada Rodríguez-Ramos, Antonio Guerrero-Ruiz
Materials 14 (2021) 4067.
Preparation, Characterization, and Activity of Pd/PSS-Modified Membranes in the Low Temperature Dry Reforming of Methane with and without Addition of Extra Steam
Cecilia Mateos-Pedrero, Miguel A. Soria, Antonio Guerrero-Ruíz, Inmaculada Rodríguez-Ramos
Membranes 11 (2021) 518.
Tunable selectivity of Ni catalysts in the hydrogenation reaction of 5‑hydroxymethylfurfural in aqueous media: role of the carbon supports
M.V. Morales, J.M. Conesa, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Carbon 182 (2021) 265-275.
Tandem catalyst for the selective hydrogenation of butadiene with hydrogen generated by decomposition of formic acid
D.H. Carrales-Alvarado, A.B. Dongil, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Chemical Communications 57 (2021) 6479-6482.
Carbothermal generated copper-molybdenum carbide supported on graphite for the CO2 hydrogenation to methanol
A.B. Dongil, J.M. Conesa, L. Pastor-Pérez, A. Sepúlveda-Escribano, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Catalysis Science and Technology 11 (2021) 4051-4059.
Guaiacol hydrodeoxygenation in hydrothermal conditions using N-doped reduced graphene oxide (RGO) supported Pt and Ni catalysts: Seeking for economically viable biomass upgrading alternatives
S. Parrilla-Lahoz, W. Jin, L. Pastor-Perez, D. Carrales-Alvarado, J.A. Odriozola, A.B. Dongil, T.R. Reina
Applied Catalysis A, General 611 (2021) 117977.
Catalytic Reforming of Methane Over Ni–La2O3 and Ni–CeO2 Catalysts Prepared by Sol-Gel Method
Nora Yahi, Kahina Kouachi, Hanane Akram, I. Rodriguez-Ramos
Advances in Renewable Hydrogen and Other Sustainable Energy Carriers (Abdallah Khellaf, Ed.) Springer Nature Singapore Pte Ltd., 2021, pp. 47-54.
Effect of the Support Functionalization of Mono- and Bimetallic Ni/Co Supported on Graphene in Hydrodeoxygenation of Guaiacol.Elodie Blanco; Damarys Carrales-Alvarado; Ana Belen Dongil; Néstor Escalona. Industrial & Engineering Chemistry Research, 60, 18870 (2021); doi: 10.1021/ACS.IECR.1C03073
Optimizing the carburization conditions of supported rhenium carbide for guaiacol conversion. Elodie Blanco, Ana Belen Dongil, I. Tyrone Ghampson, J.L. García-Fierro, Néstor Escalona. Applied Catalysis A: General 623, 118267 (2021); doi: 10.1016/J.APCATA.2021.118267
Insights into Hydrodeoxygenation of Furfural and Guaiacol Mixture: Experimental and Theoretical Studies. Emilio C. Schiesser, Elodie Blanco, Ana Belén Dongil, Ximena Zarate, Mario Saavedra-Torres, Eduardo Schott, Roberto I. Canales, and Néstor Escalona, The Journal of Physical Chemistry C, 125, 14, 7647, (2021), doi: 10.1021/ACS.JPCC.0C11415
M.V. Morales, A. Guerrero-Ruiz, E. Castillejos, E. Asedegbega-Nieto, I. Rodríguez-Ramos
Carbon, 157 (2020) 120.
Comparison of Pd and Pd4S Based Catalysts for Partial Hydrogenation of External and Internal Butynes
Yanan Liu, Yinwen Li, James A Anderson, Junting Feng, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos, Alan John McCue, Dianqing Li
Journal of Catalysis, 383 (2020) 51-59.
Cu and Pd nanoparticles supported on a graphitic carbon material as bifunctional HER/ORR electrocatalysts
M. Nunes, D.M. Fernandes, M. V. Morales, I. Rodríguez-Ramos, A. Guerrero-Ruiz, C. Freire
Catalysis Today, 357 (2020) 279-290.
Effect of Mo promotion on the activity and selectivity of Ru/Graphite catalysts for Fischer-Tropsch synthesis
J.L. Eslava, E. Gallegos-Suárez, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Catalysis Today, 357 (2020) 185-192.
Optimization of Cu-Ni-Mn-catalysts for the conversion of ethanol to butanol
C. Lopez-Olmos, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Catalysis Today, 357 (2020) 132-142.
Tracking the paths for the sucrose transformations over bifunctional Ru-POM/AC catalysts
N. García-Bosch, C. Especel, A. Guerrero Ruiz, I. Rodríguez-Ramos
Catalysis Today, 357 (2020) 113-121.
Ru nanoparticles supported on N-doped reduced graphene oxide as valuable catalyst for the selective aerobic oxidation of benzyl alcohol
C.S. Ramirez-Barria, M. Isaacs, C. Parlett, K. Wilson, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Catalysis Today, 357 (2020) 8-14.
Reductive degradation of 2,4-dichlorophenoxyacetic acid using Pd/carbon with adsorption/catalysis bifunctional roles
E. Castillejos, A. Esteban-Arranz, B. Bachiller-Baeza, I. Rodríguez-Ramos, A. Guerrero-Ruiz
Catalysis Today, 357 (2020) 361-367.
Adsorption capacity of different types of carbon nanotubes towards metronidazole and dimetridazole antibiotics from aqueous solutions: effect of morphology and surface chemistry
Damarys H. Carrales-Alvarado, Roberto Leyva-Ramos, Inmaculada Rodríguez-Ramos, Esmeralda Mendoza-Mendoza, Adriana E. Moral-Rodríguez
Environmental Science and Pollution Research, 27 (2020) 17123-17137.
Effect of surface area and physical-chemical properties of graphite and graphene-based materials on their adsorption capacity towards metronidazole and trimethoprim antibiotics in aqueous solution
D.H. Carrales-Alvarado, I. Rodríguez-Ramos, R. Leyva-Ramos, E. Mendoza-Mendoza, D.E. Villela-Martínez
Chemical Engineering Journal, 402 (2020) 126155-126166.
Selective hydrogen production from formic acid decomposition over Mo carbides supported on carbon materials
D.H. Carrales-Alvarado, A.B. Dongil, J.M. Fernández-Morales, M. Fernández-García, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Catalysis Science and Technology, 10 (2020) 6790-6799.
Comparative Study of Different Acidic Surface Structures in Solid Catalysts Applied for the Isobutene Dimerization Reaction
José M. Fernández-Morales, Eva Castillejos, Esther Asedegbega-Nieto,
Ana Belén Dongil, Inmaculada Rodríguez-Ramos and Antonio Guerrero-Ruiz
Nanomaterials, 10 (2020) 1235.
Continuous catalytic condensation of ethanol into 1-butanol: the role of metallic oxides (M= MgO, BaO, ZnO and MnO) in Cu-M/graphite catalyst
Cristina Lopez-Olmos, María V. Morales, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Industrial & Engineering Chemistry Research, 59 (2020) 1626-1636.
Application of New Nanoparticle Structures as Catalysts (Editorial)
Antonio Guerrero Ruiz, Inmaculada Rodríguez-Ramos
Nanomaterials, 10 (2020) 1686; doi:10.3390/nano10091686
Clean 3,4-Dihydropyrimidones Synthesis via Biginelli Reaction over Supported Molybdenum: Structural and Textural Characteristic of αMoO3
Ouzna Kheffache, Cristina Lopez-Olmos, Inmaculada Rodríguez-Ramos, Ouiza Cherifi
Bulletin of Chemical Reaction Engineering & Catalysis, 15 (2020) 698-713; doi: 10.9767/bcrec.15.3.8264.698-713
Conversion of succinic acid over Ni and Co catalysts
M. Rojas, X. Zarate, R.I. Canales, A.B. Dongil, C. Pazo, M. Saavedra-Torres, N. Escalona,
Catalysis Today, 2020, doi: 10.1016/j.cattod.2020.04.067
Insights in supported rhenium carbide catalysts for hydroconversion of lignin-derived compounds
E. Blanco, A.B. Dongil, J.L. García-Fierro, N. Escalona,
Applied Catalysis A: General, 2020, 599, 117600-117616.
Effect of Cu and Cs in the β-Mo2C system for CO2 hydrogenation to Methanol
Ana Belén Dongil, Qi zhang, Laura Pastor-Pérez, Tomás Ramírez-Reina, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Catalysts, 10 (2020) 1213; doi:10.3390/catal10101213
Synergy between Ni and Co Nanoparticles Supported on Carbon in Guaiacol Conversion
Elodie Blanco, Ana Belen Dongil, and Néstor Escalona
Nanomaterials, 10 (2020) 2199; doi:10.3390/nano10112199
J.M. Conesa, M.V. Morales, C. López-Olmos, I. Rodríguez-Ramos, A. Guerrero-Ruiz
Applied Catalysis A, General 576 (2019) 54-64.
Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
B. Faroldi, M. A. Paviotti, M. Camino-Manjarrés, S. González-Carrazán, C. López-Olmos and I. Rodríguez-Ramos
Nanomaterials, 9 (2019) 1516.
Cu-based N-doped/undoped graphene nanocomposites as electrocatalysts for the oxygen reduction
M. Nunes, D.M. Fernandes, M. V. Morales, I. Rodríguez-Ramos, A. Guerrero-Ruiz, C. Freire
Journal of Applied Electrochemistry, 49 (2019) 693-703.
Direct sulfation of a Zr-based Metal-Organic Framework to attain strong acid catalysts
José M. Fernández-Morales, Luis A. Lozano, Eva Castillejos-López, I. Rodríguez-Ramos, A. Guerrero-Ruiz, Juan M. Zamaro
Microporous & Mesoporous Materials, 290 (2019) 109686.
Recent Progress on Transition Metal Nitrides Nanoparticles as Heterogeneous Catalysts
A.B. Dongil
Nanomaterials, 9 (2019) 1111
Upgrading the Properties of Reduced Graphene Oxide and Nitrogen-Doped Reduced Graphene Oxide Produced by Thermal Reduction toward Effcient ORR Electrocatalysts
C.S. Ramirez-Barria, Diana M. Fernandes, Cristina Freire, Elvira Villaro-Abalos, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Nanomaterials, 9 (2019) 1761.
A.B. Dongil, B. Bachiller-Baeza, E. Castillejos-Lopez, N. Escalona, A. Guerrero-Ruiz and I. Rodríguez-Ramos
Catalysis Today, 301 (2018) 141-146.
Cooperative action of heteropolyacids and carbon supported Ru catalysts for the conversion of cellulose
M. Almohalla, I. Rodríguez-Ramos, L.S. Ribeiro, J.J.M. Órfão, M.F.R. Pereira, Antonio Guerrero-Ruiz
Catalysis Today, 301 (2018) 65-71.
When the nature of surface functionalities on modified carbon dominates the dispersion of palladium hydrogenation catalysts
E. Castillejos, A. M. García-Minguillán, B. Bachiller-Baeza, I. Rodríguez-Ramos, A. Guerrero-Ruiz
Catalysis Today, 301 (2018) 248-257.
Effect of different promoter precursors in a model Ru-Cs/graphite system on the catalytic selectivity for Fischer-Tropsch reaction
José L. Eslava, Ana Iglesias-Juez, Marcos Fernández-García, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Applied Surface Science, 447 (2018) 307-314.
New Insights in the Development of Carbon Supported Ruthenium Catalysts for Hydrogenation of Levulinic Acid
Wenjing Song, M.Carmen Lozano-Martín, Esteban Gallegos-Suarez, Carolina Ramirez-Barria, Weizheng Weng, Xiaodong Yi, Belén Bachiller-Baeza, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Current Catalysis, 7 (2018) 129-137.
Polyoxotungstate@Carbon Nanocomposites as Oxygen Reduction Reaction (ORR) Electrocatalysts
Diana M. Fernandes, Hugo C. Novais, Revathi Bacsa, Philippe Serp, Belén Bachiller-Baeza, Inmaculada Rodríguez-Ramos, Antonio Guerrero-Ruiz, Cristina Freire
Langmuir, 34 (2018) 6376-6387.
Multifunctional Mixed Valence N-doped CNT@MFe2O4 Hybrid Nanomaterials: From Engineered One-Pot Coprecipitation to Application in Energy Storage Paper Supercapacitors
Clara Pereira, Rui S. Costa, Laury Lopes, Belén Bachiller-Baeza, Inmaculada Rodríguez-Ramos, Antonio Guerrero-Ruiz, Pedro B. Tavares, Cristina Freire, André M. Pereira
Nanoscale, 10 (2018) 12820-12840.
Fructose transformations in ethanol using carbon supported polyoxometalate acidic solids for 5-Etoxymethylfurfural production
Nadia García-Bosch, Belén Bachiller-Baeza, Inmaculada Rodríguez-Ramos, Antonio Guerrero-Ruiz
ChemCatChem, 10 (2018) 3746-3753.
Optimization of ruthenium based catalysts for the aqueous phase hydrogenation of furfural to furfuryl alcohol
Carolina Ramirez-Barria, Mark Isaacs, Karen Wilson, Antonio Guerrero-Ruiz, Inmaculada Rodríguez-Ramos
Applied Catalysis A: General, 563 (2018) 177-184.
Continuous gas phase condensation of bioethanol to 1‐butanol over bifunctional Pd/Mg and Pd/Mg‐carbon catalysts
Cristina López-Olmos, Maria Virtudes Morales, Antonio Guerrero-Ruiz, Carolina Ramirez-Barria, Esther Asedegbega-Nieto, Inmaculada Rodriguez-Ramos
ChemSusChem, 11 (2018) 3502-3511.
M.V. Morales, M. Rocha, C. Freire, E. Asedegbega-Nieto, E. Gallegos-Suarez, I. Rodríguez-Ramos and A. Guerrero-Ruiz
Carbon, 111 (2017) 150-161.
Effect of surfactant concentration on the morphology of MoxSy nanoparticles prepared by a solvothermal route
Hanane Akram, Cecilia Mateos-Pedrero, Esteban Gallegos-Suarez, Tarik Chafik, Antonio Guerrero-Ruiz and Inmaculada Rodríguez-Ramos
Green Processing and Synthesis, 6 (2017) 161-171.
PMo11V@N-CNT electrochemical properties and its application as electrochemical sensor for determination of acetaminophen
Diana M. Fernandes, Marta Nunes, Belén Bachiller-Baeza, Inmaculada Rodríguez-Ramos, Antonio Guerrero-Ruiz, Cristina Delerue-Matos, Cristina Freire
Journal of Solid State Electrochemistry, 21 (2017) 1059-1068.
Effect of the metal precursor on the catalytic performance of the Ru/KL system for the ethanol transformation reactions
M. Almohalla, E. Gallegos-Suárez, A. Arcoya, J. Alvarez Rodriguez, I. Rodriguez-Ramos, A. Guerrero-Ruiz
Applied Catalysis A: General, 535 (2017) 61-68.
Ruthenium particle size and cesium promotion effects in Fischer-Tropsch synthesis over high-surface-area graphite supported catalysts
José L. Eslava, Xiaohui Sun, Jorge Gascon, Freek Kapteijn and Inmaculada Rodríguez-Ramos
Catalysis Science & Technology, 7 (2017) 1235-1244.
Comparative study of three heteropolyacids supported on carbon materials as catalysts for ethylene production from bioethanol
M. Almohalla, I. Rodríguez-Ramos and A. Guerrero-Ruiz
Catalysis Science & Technology, 7 (2017) 1892-1901.
Effect of Lanthanum promoter on the catalytic performance of Levulinic acid hydrogenation over Ru/Carbon fiber catalyst
Wenjing Song, Zhou Chen, Weikun Lai, I. Rodríguez-Ramos, Xiaodong Yi, Weizheng Weng and Weiping Fang
Understanding the role of oxygen surface groups; the key for a smart ruthenium-based carbon-supported heterogeneous catalyst design and synthesis
F.R. García-García, Esteban Gallegos-Suarez, M. Fernández-García, A. Guerrero-Ruiz, I. Rodríguez-Ramos
Applied Catalysis A: General, 544 (2017) 66-76.
Selective hydrogenation of mixed alkyne/alkene streams at elevated pressure over a palladium sulfide catalyst
Alan J. Mccue, Antonio Guerrero-Ruiz, Carolina Ramirez-Barria, Inmaculada Rodríguez-Ramos, James A. Anderson
Journal of Catalysis, 355 (2017) 40-52.
Direct catalytic effect of nitrogen functional groups exposed on graphenic materials when acting cooperatively with Ru nanoparticles
C. Ramirez-Barria, C. López-Olmos, A. Guerrero-Ruiz, I. Rodríguez Ramos
RSC Advances, 7 (2017) 44568-44577.
Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
B. Faroldi, J. Múnera, J.M. Falivene, I. Rodríguez Ramos, A. Gutierrez García, L. Tejedor Fernández, S. Gonzalez Carrazán, L. Cornaglia
International Journal of Hydrogen Energy, 42 (2017) 16127-16138.
CuPd Bimetallic Nanoparticles Supported on Magnesium Oxide as an Active and Stable Catalyst for the Reduction of 4-Nitrophenol to 4-Aminophenol
María V. Morales, José M. Conesa, Inmaculada Rodríguez-Ramos, Mariana Rocha, Cristina Freire and Antonio Guerrero-Ruiz
International Journal of Green Technology, 3 (2017) 51-62.
Patentes
- A.B. Dongil de Pedro, I. Rodríguez Ramos, A. Morterra Canga. Método catalítico para la síntesis de furfuril alcohol a partir de furfural en fase gaseosa empleando ácido fórmico como fuente de hidrógeno. Patent: 202230850, Spain 2022. Holder entity: CSIC
- A. Guerrero-Ruiz, Eva Castillejos, Belén Bachiller-Baeza, I. Rodríguez-Ramos, M. Fernández-García, A. Iglesias-Juez. Procedimiento de obtención de nanopartículas de Pd soportadas en materiales de carbono y aplicación de las mismas en hidrogenación selectiva de poliolefinas e hidrocarburos acetilénicos. Patent P201400992, Spain, 2014. Holder Entitiy: UNED-CSIC.
- M. Fernández-García, A. Kubacka, I. Rodríguez-Ramos, E. Gallegos-Suarez, A. Guerrero-Ruiz. Catalizador sólido ternario para la reacción de reformado de glicerol; procedimiento de preparación y utilización. Patent P201331786, Spain, 2013. Holder entity: UNED-CSIC
- M. Fernández García, I. Rodríguez Ramos, A. Kubacka. Catalizador de M-Cu-Ce para la reaccion de desplazamiento de gas de agua (WGS). Patent: P 201131893, Spain 2011. Holder entity: CSIC