Publicaciones 2022

Transformation of CoFe2O4 spinel structure into active and robust CoFe alloy/N-doped carbon electrocatalyst for oxygen evolution reaction

Autores: Gebreslase, GA; Martinez-Huerta, MV; Sebastian, D; Lazaro, MJ

Artículo.
J. Colloid Interface Sci.. vol: 625. page: 0021-9797.
Fecha: NOV. 2022.
Doi: 10.1016/j.jcis.2022.06.005.

Resumen:
Electrochemical water splitting is an environmentally benign technology employed for H-2 production; however, it is critically hampered by the sluggish kinetics of the oxygen evolution reaction (OER) at the positive electrode. In this work, nitrogen-doped carbon-coated CoFe electrocatalysts [read more]

2022-07-15T11:10:00+02:00Categories: Destacados, Publicaciones 2022|Tags: , |

Eco-friendly mechanochemical synthesis of titania-graphene nanocomposites for pesticide photodegradation

Autores: Gonzalez, VJ; Vazquez, E; Villajos, B; Tolosana-Moranchel, A; Duran-Valle, C; Faraldos, M; Bahamonde, A

Artículo.
Sep. Purif. Technol.. vol: 289. page: 1383-5866.
Fecha: may-15. 2022.
Doi: 10.1016/j.seppur.2022.120638.

Resumen:
Titania graphene hybrid nanocomposites (TiO2-FLG) synthesized from graphite and TiO2 precursors, in a simple and sustainable approach via a three-step method, including the mechanochemical treatment of pre-synthesized FLG and TiO2 NPs are efficient [read more]

2022-06-08T09:23:05+02:00Categories: Destacados, Publicaciones 2022|Tags: , |

Efficient Production of Solar Hydrogen Peroxide Using Piezoelectric Polarization and Photoinduced Charge Transfer of Nanopiezoelectrics Sensitized by Carbon Quantum Dots

Autores: Zhou, XF; Yan, F; Lyubartsev, A; Shen, B; Zhai, JW; Conesa, JC; Hedin, N

Artículo; Early Access.
Adv. Sci.. vol: . page: .
Fecha: . .
Doi: 10.1002/advs.202105792.

Resumen:
Piezoelectric semiconductors have emerged as redox catalysts, and challenges include effective conversion of mechanical energy to piezoelectric polarization and achieving high catalytic activity. The catalytic activity can be enhanced by simultaneous irradiation [read more]

Single adsorption of diclofenac and ronidazole from aqueous solution on commercial activated carbons: effect of chemical and textural properties

Autores: Moral-Rodriguez, AI; Leyva-Ramos, R; Mendoza-Mendoza, E; Diaz-Flores, PE; Carrales-Alvarado, DH; Alexandre-Franco, MF; Fernandez-Gonzalez, C

Artículo; Early Access.
Environ. Sci. Pollut. Res.. vol: . page: 0944-1344.
Fecha: . .
Doi: 10.1007/s11356-021-17466-7.

Resumen:
The importance of the textural and physicochemical characteristics upon the adsorption capacity of the commercial activated carbons (ACs) Coconut, Wood, Merck, Darco, and Norit towards ronidazole (RNZ) and diclofenac (DCF) [read more]

2022-05-05T15:54:26+02:00Categories: Publicaciones 2022|Tags: |

One-Pot Conversion of Glucose into 5-Hydroxymethylfurfural using MOFs and Bronsted-Acid Tandem Catalysts

Autores: Lara-Serrano, M; Morales-delaRosa, S; Campos-Martin, JM; Abdelkader-Fernandez, VK; Cunha-Silva, L; Balula, SS

Artículo; Early Access.
Adv. Sustain. Syst.. vol: . page: 2366-7486.
Fecha: . .
Doi: 10.1002/adsu.202100444.

Resumen:
The direct conversion reaction of glucose to 5-hydroxymethylfurfural (HMF) is studied using metal organic framework (MOF) as Lewis-acid catalysts and a polyoxometalate (POM), silicotungstic acid, as a Brensted-type acid with a mixture of [read more]

Photodegradation of 2-propanol in gas phase over zirconium doped TiO2: Effect of Zr content

Autores: Jedidi, W; Arfaoui, J; Caudillo-Flores, U; Munoz-Batista, MJ; Ksibi, Z; Kubacka, A; Ghorbel, A; Fernandez-Garcia, M

Artículo.
J. Photochem. Photobiol. A-Chem.. vol: 427. page: 1010-6030.
Fecha: may-01. 2022.
Doi: 10.1016/j.jphotochem.2022.113774.

Resumen:
The photocatalytic activity in the 2-propanol degradation, under UV and sunlight (SL)-type irradiations, of a series of Zr-TiO(2 )materials, prepared using the sol-gel method, with a Zr content ranging from [read more]

2022-05-05T19:00:56+02:00Categories: Destacados, Publicaciones 2022|Tags: , |

Synthesis of cyclohexylphenol via phenol hydroalkylation using Co2P/zeolite catalysts

Autores: Gutierrez-Rubio, S; Shamzhy, M; Cejka, J; Serrano, DP; Coronado, JM; Moreno, I

Artículo.
Catal. Today. vol: 390. page: 0920-5861.
Fecha: may-01. 2022.
Doi: 10.1016/j.cattod.2021.11.039.

Resumen:
Cyclohexylphenol (CHP) is a high added-value chemical, extensively used for the preparation of dyes, resins and biocides. This molecule is currently synthetized by phenol alkylation with cyclohexene/cyclohexanol using highly polluting mineral Bronsted acids as catalysts. The [read more]

Semiamorphous Fe-BDC: The missing link between the highly-demanded iron carboxylate MOF catalysts

Autores: Flores, JG; Delgado-Garcia, R; Sanchez-Sanchez, M

Artículo.
Catal. Today. vol: 390. page: 0920-5861.
Fecha: may-01. 2022.
Doi: 10.1016/j.cattod.2021.11.004.

Resumen:
Porous Fe carboxylates are amongst the most promising MOF-based materials due to their low price, low toxicity, metal environments (including open metal sites) and remarkable (meso)porosity variety. Fe-MOFs based on the cluster [Fe3O(X)(solvent)(2)](6+), that is, MIL-101(Fe), MIL-100(Fe) and semiamorphous Fe-BTC, are of [read more]

Ti-PMO materials as selective catalysts for the epoxidation of cyclohexene and vernonia oil

Autores: Awoke, Y; Chebude, Y; Diaz, I

Artículo.
Catal. Today. vol: 390. page: 0920-5861.
Fecha: may-01. 2022.
Doi: 10.1016/j.cattod.2021.10.010.

Resumen:
The aim of this study is to obtain Ti-containing Periodic Mesoporous Organosilica (PMO) materials with catalytic activity in epoxidation reactions. Characterization of the PMO materials using X ray diffraction, N-2 sorption isotherms, chemical analysis (ICP-OES) and UV-vis spectroscopy reveals that the Ti-PMO [read more]

One-pot laccase@MOF biocatalysts efficiently remove bisphenol A from water

Autores: Molina, MA; Diez-Jaen, J; Sanchez-Sanchez, M; Blanco, RM

Artículo.
Catal. Today. vol: 390. page: 0920-5861.
Fecha: may-01. 2022.
Doi: 10.1016/j.cattod.2021.10.005.

Resumen:
fThe presence of bisphenol A (BPA) in wastewater, its toxicity and the hardness for its complete degradation constitutes a serious environmental problem and a scientific challenge. The enzyme laccase is an oxidoreductase capable of oxidizing phenolic compounds, being one of [read more]

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