Multidisciplinary

Nanosized-bulk V-containing mixed-oxide catalysts: a strategy for the improvement of the catalytic materials properties

Authors: Lopez-Medina, R; Guerrero-Perez, MO; Banares, MA

Article.
New J. Chem.. vol: 43. page: 1144-0546.
Date: DEC 7. 2019.
Doi: 10.1039/c9nj01637f.

Abstract:
A series of nanosized-bulk-supported Mo-V-Nb-Te catalysts was prepared. Using a new synthesis approach, nanocrystalline aggregates of the active phase were deposited on a support. This resulted in the formation of active and selective catalysts for propane oxidation in the acrylic [read more]

2019-12-07T00:00:00+01:00Categories: Publicaciones 2019|Tags: , |

Methanol Synthesis from CO2: A Review of the Latest Developments in Heterogeneous Catalysis

Authors: Guil-Lopez, R; Mota, N; Llorente, J; Millan, E; Pawelec, B; Fierro, JLG; Navarro, RM

Review.
Materials. vol: 12. page: .
Date: DEC. 2019.
Doi: 10.3390/ma12233902.

Abstract:
Technological approaches which enable the effective utilization of CO2 for manufacturing value-added chemicals and fuels can help to solve environmental problems derived from large CO2 emissions associated with the use of fossil fuels. One of [read more]

Direct sulfation of a Zr-based metal-organic framework to attain strong acid catalysts

Authors: Fernandez-Morales, JM; Lozano, LA; Castillejos-Lopez, E; Rodriguez-Ramo, I; Guerrero-Ruiz, A; Zamaro, JM

Article.
Microporous Mesoporous Mat.. vol: 290. page: 1387-1811.
Date: DEC. 2019.
Doi: 10.1016/j.micromeso.2019.109686.

Abstract:
The application of Metal-Organic Frameworks (MOFs) in gas phase heterogeneous catalysis is still not widely spread because of their limited stability under reaction conditions. Obtaining stable acidic MOFs to be used in reactions that demand [read more]

Methanol Synthesis from CO2: A Review of the Latest Developments in Heterogeneous Catalysis

Authors: Guil-Lopez, R; Mota, N; Llorente, J; Millan, E; Pawelec, B; Fierro, JLG; Navarro, RM

Review.
Materials. vol: 12. page: .
Date: DEC. 2019.
Doi: 10.3390/ma12233902.

Abstract:
Technological approaches which enable the effective utilization of CO2 for manufacturing value-added chemicals and fuels can help to solve environmental problems derived from large CO2 emissions associated with the use of fossil fuels. One of [read more]

Upgrading the Properties of Reduced Graphene Oxide and Nitrogen-Doped Reduced Graphene Oxide Produced by Thermal Reduction toward Efficient ORR Electrocatalysts

Authors: Ramirez-Barria, CS; Fernandes, DM; Freire, C; Villaro-Abalos, E; Guerrero-Ruiz, A; Rodriguez-Ramos, I

Article.
Nanomaterials. vol: 9. page: .
Date: DEC. 2019.
Doi: 10.3390/nano9121761.

Abstract:
N-doped (NrGO) and non-doped (rGO) graphenic materials are prepared by oxidation and further thermal treatment under ammonia and inert atmospheres, respectively, of natural graphites of different particle sizes. An extensive characterization of graphene materials points out that [read more]

Site-selective modification of tryptophan and protein tryptophan residues through PdNP bionanohybrid-catalysed C-H activation in aqueous media

Authors: Perez-Rizquez, C; Abian, O; Palomo, JM

Article.
Chem. Commun.. vol: 55. page: 1359-7345.
Date: nov-07. 2019.
Doi: 10.1039/c9cc06971b.

Abstract:
Herein we report for the first time the site-selective C-H bond arylation of tryptophan and tryptophan residues in proteins in aqueous media at room temperature by using a PdNP bionanohybrid as a heterogeneous catalyst. The reaction proceeds using a stable aryldiazonium salt [read more]

2019-11-07T00:00:00+01:00Categories: Publicaciones 2019|Tags: , |

Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content

Authors: Faroldi, B; Paviotti, MA; Camino-Manjarres, M; Gonzalez-Carrazan, S; Lopez-Olmos, C; Rodriguez-Ramos, I

Article.
Nanomaterials. vol: 9. page: .
Date: NOV. 2019.
Doi: 10.3390/nano9111516.

Abstract:
Formic acid, a major product of biomass processing, is regarded as a potential liquid carrier for hydrogen storage and delivery. The catalytic dehydrogenation of FA to generate hydrogen using heterogeneous catalysts is of great interest. Ni based [read more]

Ultrasmall Cs-AlMCM-41 basic catalysts: Effects of aluminum addition on their physico-chemical and catalytic properties

Authors: Ng, EP; Abdullahi, H; Wong, KL; Gines-Molina, MJ; Maireles-Torres, P; Rigolet, S; Daou, TJ; Chia, S; Lee, HL

Article.
Microporous Mesoporous Mat.. vol: 288. page: 1387-1811.
Date: nov-01. 2019.
Doi: 10.1016/j.micromeso.2019.109599.

Abstract:
In this study, ultra-small MCM-41 mesoporous solids (< 30 nm) were synthesized using colloidal silica and cesium hydroxide as cheap silica source and mineralize; respectively. Four samples with a [read more]

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