Physical

Authors: Losada-Garcia, N; Urriolabeitia, EP; Palomo, JM

Article; Early Access.
ChemCatChem. vol: . page: 1867-3880.
Date: . .
Doi: 10.1002/cctc.202201632.

Abstract:
Solid-phase lipase/metal nanobiohybrids, generated by growth of copper nanoparticles on enzyme matrixes immobilized on graphene, were used as heterogeneous catalysts with dual-activity for the regioselective production of 2,3,4-triacetyl-D-gluconic acid from alpha-peracetylated-glucose in a one-pot parallel process combining a lipase-mediated regioselective hydrolytic [read more]

Authors: Domestici, C; Wu, YQ; Hilberath, T; Alcalde, M; Hollmann, F; Macchioni, A

Article; Early Access.
ChemCatChem. vol: . page: 1867-3880.
Date: . .
Doi: 10.1002/cctc.202201623.

Abstract:
Unspecific peroxygenases (UPOs) are promising biocatalysts for oxyfunctionalisation reactions, owing to their simplicity of handling, stability and robustness. A limitation of using UPOs on a large scale is their deactivation in the presence of even [read more]

Authors: Alagoz, D; Varan, NE; Yildirim, D; Fernandez-Lafuente, R

Article.
Mol. Catal.. vol: 531. page: 2468-8231.
Date: OCT. 2022.
Doi: 10.1016/j.mcat.2022.112647.

Abstract:
The xylanase from Thermomyces lanuginosus was immobilized following very different protocols, using 3-aminopropyl (Xyl/CNT-NH2) and carboxylic acid (Xyl/CNT-C) functionalized multi-walled carbon nanotubes or after glutaraldehyde activation of CNT-NH2 (Xyl/CNT-Glu). It was also immobilized on carboxylic acid functionalized multi-walled carbon nanotubes [read more]

Authors: Ruiz, MG; Casados, DAS; Pliego, JA; Alvarez, CM; de Andres, ES

Article; Early Access.
Catal. Lett.. vol: . page: 1011-372X.
Date: . .
Doi: 10.1007/s10562-022-04181-2.

Abstract:
This paper presents a study of the use of zeolitic catalysts and modified zeotypes for the reaction of transformation of methanol to hydrocarbons (MTH). Materials of the aluminophosphate type MeAPO-36 where Me is Zn, Mg [read more]

Authors: Carballares, D; Rocha-Martin, J; Fernandez-Lafuente, R

Article.
Catalysts. vol: 12. page: .
Date: SEP. 2022.
Doi: 10.3390/catal12091009.

Abstract:
The first step of the inactivation of the enzyme D-amino acid oxidase (DAAO) from porcine kidney at pH 5 and 7 is the enzyme subunit dissociation, while FAD dissociation has not a relevant role. At pH 9, both dissociation phenomena affect the enzyme [read more]

Authors: Garcia-Perez, D; Lopez-Garcia, A; Renones, P; Alvarez-Galvan, MC; Campos-Martin, JM

Article.
Mol. Catal.. vol: 529. page: 2468-8231.
Date: AUG. 2022.
Doi: 10.1016/j.mcat.2022.112556.

Abstract:
Heterogeneous catalysts based on alumina-supported tungsten oxides (15 wt% W) with different loadings of nickel (0.5, 1, 2, 4, 6, 8 and 10 wt% Ni) were selected to study the influence of Ni loading on the hydroisomerization of [read more]

Authors: Naapuri, JM; Losada-Garcia, N; Rothemann, RA; Pichardo, MC; Prechtl, MHG; Palomo, JM; Deska, J

Article; Early Access.
ChemCatChem. vol: . page: 1867-3880.
Date: . .
Doi: 10.1002/cctc.202200362.

Abstract:
Lipase/metal nanobiohybrids, generated by growth of silver or gold nanoparticles on protein matrixes are used as highly effective dual-activity heterogeneous catalysts for the production of enantiomerically enriched 2,5-dihydrofurans from allenic acetates in a [read more]

Authors: Blanco-Brieva, G; Desmedt, F; Miquel, P; Campos-Martin, JM; Fierro, JLG

Article.
Catalysts. vol: 12. page: .
Date: JUL. 2022.
Doi: 10.3390/catal12070796.

Abstract:
We have studied the direct synthesis of hydrogen peroxide using a catalytic system consisting of palladium supported on silica bifunctionalized with sulfonic acid groups and bromide in the absence of acid and halide promoters in solution. Catalysts with several [read more]